Dynamic Nuclear Polarization of Oxygen-17.
نویسندگان
چکیده
Oxygen-17 detected DNP NMR of a water/glycerol glass enabled an 80-fold enhancement of signal intensities at 82 K, using the biradical TOTAPOL. The >6,000-fold savings in acquisition time enables (17)O-(1)H distance measurements and heteronuclear correlation experiments. These experiments are the initial demonstration of the feasibility of DNP NMR on quadrupolar (17)O.
منابع مشابه
Efficient room-temperature nuclear spin hyperpolarization of a defect atom in a semiconductor.
Nuclear spin hyperpolarization is essential to future solid-state quantum computation using nuclear spin qubits and in highly sensitive magnetic resonance imaging. Though efficient dynamic nuclear polarization in semiconductors has been demonstrated at low temperatures for decades, its realization at room temperature is largely lacking. Here we demonstrate that a combined effect of efficient sp...
متن کاملDynamic nuclear polarization at 9T using a novel 250GHz gyrotron microwave source
In this communication, we report enhancements of nuclear spin polarization by dynamic nuclear polarization (DNP) in static and spinning solids at a magnetic field strength of 9T (250 GHz for g = 2 electrons, 380 MHz for 1H). In these experiments, 1H enhancements of up to 170 ± 50 have been observed in 1-13C-glycine dispersed in a 60:40 glycerol/water matrix at temperatures of 20 K; in addition,...
متن کاملEffect of ageing heat treatment on corrosion behaviorof 17-4 PH stainless steel in 3.5% NaCl
The 17-4PH alloy is a martensitic stainless steel with 3–5 wt% Cu, strengthened by the precipitation hardening. Due to excellent mechanical properties, corrosion resistance and ease of heat treatment, this alloy has unique applications in nuclear power plants and marine constructions. In this paper, the influence of ageing heat treatment, solution annealing followed by ageing at 480, 550 and 62...
متن کاملDynamic Nuclear Polarization of [superscript 17] O: Direct Polarization
Dynamic nuclear polarization of 17O was studied using four different polarizing agents – the biradical TOTAPOL, and the monoradicals trityl and SA-BDPA, as well as a mixture of the latter two. Field profiles, DNP mechanisms and enhancements were measured to better understand and optimize directly polarizing this low-gamma quadrupolar nucleus using both monoand bi-radical polarizing agents. Enha...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- The journal of physical chemistry letters
دوره 3 15 شماره
صفحات -
تاریخ انتشار 2012